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5.1.1.1Atoms, elements and compounds

AQA GCSE Combined Science Foundation (8464), Foundation tier · Chemistry › Atomic structure and the periodic table › A simple model of the atom, symbols, relative atomic mass,

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The basic language of chemistry: atoms, elements and compounds, chemical symbols and formulae, and how to write word equations and balanced symbol equations. It is tested all through both papers, often as tick-box, 'name the compound' and 'balance the equation' questions.

Key facts

  • Atom: the smallest part of an element that can exist
  • Element: contains only one sort of atom
  • Compound: two or more elements chemically combined in fixed proportions
  • A compound can only be separated into its elements by chemical reactions
  • -ide: usually just the two elements named, e.g. NaCl sodium chloride (hydroxide, OH−, is an exception)
  • -ate: oxygen is also present, e.g. CaCO3 calcium carbonate
  • Balanced equation: same number of each type of atom on both sides
  • Elements made of two-atom molecules: H2, N2, O2, F2, Cl2, Br2, I2

Notes

Atoms and elements

  • All substances are made of atoms. An atom is the smallest part of an element that can exist.
  • An element contains only one sort of atom. There are about 100 different elements, all listed in the periodic table.
  • Each element has a chemical symbol: one capital letter, sometimes followed by one lower-case letter, e.g. C (carbon), Cl (chlorine), Cu (copper).
  • Some elements exist as molecules of two atoms, e.g. H2, N2, O2 and Cl2. They are still elements, because all the atoms are the same.

Compounds

diagram
  • A compound contains two or more elements chemically combined in fixed proportions. Water is always H2O: two hydrogen atoms for every oxygen atom.
  • elementone type of atomelementmolecules, e.g. O2compounddifferent atoms bonded
    Each circle is an atom. A compound has two or more different atoms chemically combined.
  • Compounds are made from elements by chemical reactions. A reaction always makes at least one new substance and often has an energy change you can detect, e.g. the mixture gets hot.
  • A compound can only be separated into its elements by another chemical reaction, not by physical processes such as filtering or distilling.
  • Naming: a metal with one non-metal ends in -ide (MgO, magnesium oxide). An ending of -ate means oxygen is also present (CuSO4, copper sulfate; KNO3, potassium nitrate).

Formulae and equations

diagram
  • A formula shows which elements are in a substance and the ratio of their atoms. In 2H2O the large 2 means two molecules; the small 2 means two H atoms in each molecule.
  • Everything inside brackets is multiplied by the number after them: Ca(OH)2 contains 1 Ca, 2 O and 2 H.
  • A word equation names the reactants and products: magnesium + oxygen → magnesium oxide.
  • A balanced symbol equation has the same number of atoms of each element on both sides, because atoms are not made or destroyed in a reaction: 2Mg + O2 → 2MgO.
  • HHHH+OOHHOHHO2H2O22H2O4 H atoms, 2 O atoms4 H atoms, 2 O atoms
    Balanced: 2H2 + O2 → 2H2O. The atoms are rearranged, not made or destroyed.
  • To balance, change only the large numbers in front of formulae. Never change a small number in a formula: that would make it a different substance.

How to answer each type of question

Identify elements and compounds, and explain why

1 to 2 marksGrade 3
  1. Element: only one type of atom (single atoms, or molecules such as O2).
  2. Compound: two or more different types of atom bonded together.
  3. To explain 'why it is a compound', give both ideas: different elements, and chemically combined.

Example. The formulae of four substances are: N2, NaF, Fe, SO2
(a) Give the formulae of the two elements.
(b) SO2 is a compound. Explain why.

Show the model answerHide the model answer
(a) N2 and Fe (1) (both needed)
(b) It contains two different elements, sulfur and oxygen (1), which are chemically combined / bonded together (1).

Name a compound or write a word equation

1 markGrade 4
  1. Name the metal first, unchanged.
  2. Change the non-metal ending to -ide, or use the -ate name for a group containing oxygen (sulfate, carbonate, nitrate).
  3. In a word equation, use an arrow (→), never an equals sign.

Example. (a) Potassium reacts with bromine to form potassium bromide. Write a word equation for the reaction.
(b) Name the compound with the formula MgSO4.

Show the model answerHide the model answer
(a) potassium + bromine → potassium bromide (1)
(b) magnesium sulfate (1)

Balance a symbol equation

1 markGrade 5
  1. Count the atoms of each element on each side.
  2. Balance one element at a time, starting with one that appears in only one substance on each side.
  3. Leave elements that are on their own (e.g. O2) until last.
  4. Recount every element at the end.

Example. Balance the equation for the reaction of aluminium with oxygen.
....Al + ....O2 → ....Al2O3

Show the model answerHide the model answer
4Al + 3O2 → 2Al2O3 (1)
Check: Al 4 on each side; O 6 on each side.

Don’t lose marks

  • Changing the small numbers in a formula (e.g. writing H2O2 for water) to balance an equation. This changes the substance.
  • Naming NaCl 'sodium chlorine'. The compound is sodium chloride.
  • Saying a compound contains elements that are 'mixed'. They are chemically combined (bonded).
  • Wrong capital letters: CO (carbon monoxide) and Co (cobalt) are different substances.
  • Using = instead of → in an equation.

More tips

Memory tricks

  • Symbols: one capital letter, then at most one lower-case letter. Co is cobalt; CO is carbon monoxide.
  • Two-atom elements: 'HON plus the halogens': H2, O2, N2 and all of Group 7 (F2, Cl2, Br2, I2).
  • When balancing, write a tally of each element under both sides and update it every time you change a number.

Exam technique

  • To explain why a substance is a compound, use both key phrases: 'two or more different elements' and 'chemically combined'.
  • Copy formulae from the question exactly as they are printed; don't change them to make balancing easier.
  • Balancing questions are usually 1 mark for the whole equation, so check every element before you move on.

What each grade needs

What you need to be able to do, from the first marks up to the top grade.

  1. Grade 3
    Tell elements from compounds using formulaeAn element's formula has one symbol (Fe, O2); a compound's formula has two or more different symbols (CO2, NaCl).
  2. Grade 3
    Recall symbols of the first 20 elementsAlso the Group 1 and Group 7 elements and others in the course, with the correct capital and lower-case letters.
  3. Grade 4
    Name compounds from their formulaeA metal with a non-metal ends in -ide (NaCl, sodium chloride); -ate means oxygen is also present (CaCO3, calcium carbonate).
  4. Grade 4
    Count the atoms in a formulaIn Ca(OH)2 the 2 multiplies everything in the brackets: 1 Ca, 2 O and 2 H, so 5 atoms.
  5. Grade 5
    Write word equations for reactionsReactants on the left, products on the right, joined by an arrow, e.g. magnesium + oxygen → magnesium oxide.

Quick recall

Cover the answers and test yourself. The app has these as flashcards that come back just before you'd forget them.

Chalk is mainly calcium carbonate. The formula of calcium carbonate is CaCO3. Give the chemical symbol for calcium.
Ca
Lithium is the only Group 1 metal that reacts with nitrogen at room temperature. The product is lithium nitride, Li3N. Write a word equation for the reaction.
lithium + nitrogen → lithium nitride
When a mixture of aluminium powder and iron(III) oxide is ignited, it glows white hot and molten iron is formed.
2Al + Fe2O3 → Al2O3 + 2Fe
Name the compound Al2O3.
aluminium oxide
The iron filings in the mixture were attracted to the magnet.
Explain why.
The iron and sulfur are not chemically combined, so the iron keeps its magnetic property.

Sample questions

Written for this site in the style of AQA exam questions. They are not taken from real past papers.

Question 1Easy5 marks
Chalk is mainly calcium carbonate. The formula of calcium carbonate is CaCO3.
(a) Which of these substances is an element?
Tick (✓) one box.[1]
  • Carbon dioxide
  • Magnesium
  • Sodium chloride
  • Water
(b) Give the chemical symbol for calcium.[1]
(c) Name the three elements in calcium carbonate.[1]
(d) How many atoms are shown in the formula CaCO3?[1]
(e) Which statement describes an atom?
Tick (✓) one box.[1]
  • A particle that always has an overall positive charge
  • The smallest part of an element that can exist
  • Two or more elements chemically combined
  • A substance that contains more than one type of particle
Show the answer and mark scheme
(a) Answer: Magnesium
(b) Answer: Ca
  • Ca
(c) Answer: calcium, carbon and oxygen
  • calcium, carbon and oxygen
(d) Answer: 5
  • 5
(e) Answer: The smallest part of an element that can exist
Question 2Medium5 marks
Lithium is the only Group 1 metal that reacts with nitrogen at room temperature. The product is lithium nitride, Li3N.
(a) Write a word equation for the reaction.[1]
(b) Balance the symbol equation for the reaction.
....Li + N2 → ....Li3N[1]
(c) Compounds contain elements in fixed proportions.
Give the ratio of lithium atoms to nitrogen atoms in lithium nitride.[1]
(d) Explain why lithium nitride can only be separated into lithium and nitrogen by a chemical reaction.[2]
Show the answer and mark scheme
(a) Answer: lithium + nitrogen → lithium nitride
  • lithium + nitrogen → lithium nitride
(b) Answer: 6Li + N2 → 2Li3N
  • 6Li + N2 → 2Li3N
(c) Answer: 3 : 1
  • 3 : 1
(d) Answer: The lithium and nitrogen are chemically combined (bonded); physical processes such as filtration or distillation cannot break these bonds.
  • the elements / lithium and nitrogen are chemically combined / bonded
  • physical processes (such as filtration or distillation) cannot separate them / bonds must be broken (by a chemical reaction)

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